Moisture Sorption/Desorption of Protein Fibers

    November 2012 in “ Thermochimica Acta
    Clara Barba, Meritxell Martı́, Julieta Carilla, A. M. Manich, Luísa Coderch
    TLDR Internal lipids in keratin fibers, like wool and hair, reduce water absorption and release.
    The study evaluated the water adsorption and desorption behavior of keratin fibers, specifically wool and human hair, with and without internal lipids. It was found that the isotherms for these fibers exhibited a characteristic hysteresis between uptake and desorption. Wool fibers had lower diffusion coefficients compared to hair fibers, which was attributed to the higher proportion of ceramides in wool lipids, leading to reduced water penetration. Lipid extraction increased diffusion coefficients, highlighting the role of lipids in maintaining water permeability. The study used the GAB model to analyze variations in monolayer sorption capacity, emphasizing the importance of internal lipids in the water sorption properties of keratin fibers.
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