Laccase-Catalyzed Poly(Tyrosine) Grafting Improves The Performance Of Wool

    January 2024 in “ Authorea (Authorea)
    Yu Liu, Jennifer Noro, Jie Li, Carla Silva, Jing Su, Artur Cavaco‐Paulo
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    Studysummary This study found that laccase-assisted grafting of poly(tyrosine) onto wool materials improved shrinkage resistance and mechanical properties while causing minor decreases in crystallinity and thermal resistance, suggesting a potential "green" approach to enhance wool durability.
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    The study demonstrates that laccase-catalyzed poly(tyrosine) grafting significantly enhances wool's mechanical properties, hydrophilicity, and shrink-resistance without the environmental drawbacks of traditional chlorine-Hercosett treatments. Using laccase from Myceliophthora thermophila and polyethylene glycol (PEG) as a template, the process oxidizes tyrosine to di-tyrosine and other oligomers, which are grafted onto wool fibers. Analytical techniques confirmed the successful grafting and structural improvements, making this an eco-friendly and effective alternative for wool treatment.
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